University of Chemical Technology and Metallurgy

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Browsing University of Chemical Technology and Metallurgy by Author "Abdelhafiz M."

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    A Comparative Azeotropic Research on Combustion of Common Ternary Systems
    (2023-01-01) Abdelhafiz M.; Hussein A.K.; Naeim I.; Shalaby A.; Azazy A.; Saleh A.; Tolba S.; Elbeih A.
    Methyl Tertiary Butyl Ether (MTBE) and Methanol are effective fuel oxygenate that boost octane number, improve fuel performance, combustion behavior and minimize environmental pollutant emissions. In the petroleum business, however, their high-water solubility restricts their use in terms of fuel homogeneity loss. This work presents a full investigation map for the status of the phase diagram for the tertiary system of MTBE-methanol-water at different temperatures; 0, 40, and 70oC, and different pressures; 1.0 and 3.0 atm, based on different compositions. Furthermore, the thermodynamic coefficient, UNIFAC-LL, was linked to the Aspen plus Version 9. After validation of the software by the real experimental data, the software was used to complete the full map at all missing conditions. Pressure does not influence the occurrence of phase transitions, but the temperature has a minor effect on the LLE. The methanol concentration at which phase separation occurred dropped from 43% to 31.2% when the temperature was lowered from 70 to 40°C. With the use of simulation, the compositions at which phase separation occurs were also discovered. Last but not least, it was observed that the thermodynamic model (UNIFAC-LL) properly predicted the behavior of the methanol-water-MTBE ternary system with less than 3% inaccuracy in the binodal curve points. Consequently, a validated phase diagram is developed to accurately predict the physical state of the MTBE-methanol-water system at ant temperature, pressure, and mole fraction of each component. Hence, it guarantees the feasibility of using this tertiary system, as an effective octane booster additive, under severe working conditions.
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    Sensitivity and Performance of Dinitroanisole (DNAN) in comparison with TNT
    (2022-01-01) Hussein A.K.; Elbeih A.; Abdelhafiz M.; Ahmed H.S.; Shalaby A.S.A.; Azazy A.; Saleh A.
    The constant search for protection the soldier during training and participation in hostilities led us to aspire to develop types of energetic materials of a special nature that qualify them to reach the maximum levels of safety during handling, transportation and uses. In this work, we focus on one of these compounds, which is the main component of the preparation of low sensitive compositions. DNAN is an explosive with low sensitivity. Preparation of DNAN in laboratory scale was performed; explosive characterization was presented. Impact and friction sensitivities of DNAN, heat of combustion and detonation velocity were specified. TGA and DSC were used to investigate the DNAN thermal behavior under specific conditions. It was concluded that sensitivity of DNAN is lower than TNT and the chosen cyclic nitramines. The detonation properties of DNAN are slightly lower than TNT however DNAN is candidate individually or with other explosives to replace TNT in low sensitive compositions to full fill the safety and security manipulation of ammunitions.