Crystallization behaviour of the systems Na2O/BaO/TiO2/SiO2/B2O3/Al2O3 and Na2O/BaO/TiO2/SiO2/B2O3/Fe2O3/Al2O3
creativework.keywords | Barium titanate, Crystallization, Dielectric glass-ceramics | |
creativework.publisher | University of Chemical Technology and Metallurgyjournal@uctm.edu | en |
dc.contributor.author | Harizanova R. | |
dc.contributor.author | Mazhdrakova A. | |
dc.contributor.author | Vladislavova L. | |
dc.contributor.author | Avdeev G. | |
dc.contributor.author | Bocker C. | |
dc.contributor.author | Gugov I. | |
dc.contributor.author | Rüssel C. | |
dc.date.accessioned | 2024-07-16T11:16:47Z | |
dc.date.accessioned | 2024-07-16T11:18:22Z | |
dc.date.available | 2024-07-16T11:16:47Z | |
dc.date.available | 2024-07-16T11:18:22Z | |
dc.date.issued | 2015-01-01 | |
dc.description.abstract | This work reports data on the synthesis of glasses in three selected compositions of each of the systems Na2O/BaO/ TiO2/SiO2/B2O3/Al2O3 and Na2O/BaO/TiO2/SiO2/B2O3/Fe2O3/Al2O3 and the preparation of glass-ceramics by applying appropriate time-temperature regimes. Crystallization of a large volume fraction of cubic BaTiO3 is observed in both systems. The phase compositions of the obtained annealed specimens are investigated by x-ray diffraction, while the microstructure of the obtained glass-ceramics is studied by optical and scanning electron microscopy. The barium titanate crystals in the samples containing iron have a size varying from ca 100 nm to some hundreds of nm. They form interconnected structures which tend to grow further for all temperature-time schedules applied. The microstructure of the annealed samples containing no iron, as proved by optical and electron scanning microscopy, is characterized by barium titanate crystals of a size of some micrometers which are uniformly dispersed in the amorphous matrix. They start to grow independently and tend to merge upon longer annealing times. | |
dc.identifier.issn | 1314-7978 | |
dc.identifier.issn | 1314-7471 | |
dc.identifier.scopus | SCOPUS_ID:84937938674 | en |
dc.identifier.uri | https://rlib.uctm.edu/handle/123456789/1111 | |
dc.language.iso | en | |
dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84937938674&origin=inward | |
dc.title | Crystallization behaviour of the systems Na2O/BaO/TiO2/SiO2/B2O3/Al2O3 and Na2O/BaO/TiO2/SiO2/B2O3/Fe2O3/Al2O3 | |
dc.type | Article | |
oaire.citation.issue | 4 | |
oaire.citation.volume | 50 |