Kinetics of nitration of cis-1,4-polybutadiene rubber in solution with nitrogen dioxide.

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creativework.keywordsKinetic Regime, Kinetics, Nitration, Polybutadiene Rubber, Reaction Mechanism, Reaction Rate, Solution
dc.contributor.authorMladenov I.
dc.contributor.authorKostov G.
dc.contributor.authorRashev V.
dc.date.accessioned2024-07-10T14:27:02Z
dc.date.accessioned2024-07-10T14:46:53Z
dc.date.available2024-07-10T14:27:02Z
dc.date.available2024-07-10T14:46:53Z
dc.date.issued1978-01-01
dc.description.abstractThe kinetics of nitration of cis-1,4-polybutadiene rubber dissolved in dichloroethane in the range of concentrations up to 2.2% was studied in a stirred cell. It was found that diffusion of nitrogen dioxide is not important and the reaction is of the first order with respect to both reactants. The overall second-order reaction rate constant was found to be about 1.1×10−5l/(gmol sec) at 303K. The obtained value for the activation energy corresponds to kinetic regime. Based on these results a reaction mechanism is proposed. © 1978, The Society of Polymer Science, Japan. All rights reserved.
dc.identifier.doi10.1295/polymj.10.451
dc.identifier.issn1349-0540
dc.identifier.issn0032-3896
dc.identifier.scopusSCOPUS_ID:0017914406en
dc.identifier.urihttps://rlib.uctm.edu/handle/123456789/49
dc.language.isoen
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0017914406&origin=inward
dc.titleKinetics of nitration of cis-1,4-polybutadiene rubber in solution with nitrogen dioxide.
dc.typeArticle
oaire.citation.issue4
oaire.citation.volume10
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