Nanoscale particle reinforcement by oligourea particles in polyurethanes - A concept to control mechanical properties

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creativework.keywordsIsocyanate prepolymer, Mechanical properties, Nanocomposite, Oligourea
creativework.publisherUniversity of Chemical Technology and Metallurgyjournal@uctm.eduen
dc.contributor.authorPeshkov V.
dc.contributor.authorHerzog M.
dc.contributor.authorBehrendt G.
dc.date.accessioned2024-07-16T11:16:45Z
dc.date.accessioned2024-07-16T11:17:56Z
dc.date.available2024-07-16T11:16:45Z
dc.date.available2024-07-16T11:17:56Z
dc.date.issued2014-01-01
dc.description.abstractWe report on a concept to obtain high properties of nanocomposites by incorporating into the polymer matrix nanoscale reactive species to reinforce the structures already at low concentrations. The materials used to study the effect of reactive organic nanofillers on properties of organic-organic nanocomposites were poly(urethane ureas) in which the urethane part consisted of long chain polyether alcohols reacted with 4,4'-diphenylmethane diisocyanate (MDI) and the urea part of oligourea particles produced either by solvolysis of flexible polyurethane foams or by a new method in which a isocyanate prepolymer is reacted with appropriate reagents with simultaneous cleavage of the pre-formed urethane bond. The combination of two polymer networks-a urethane and a urea one-result in extraordinary synergy in mechanical properties. The properties can indeed be tailored by changing the volume fraction, shape, and size of the filler particle.
dc.identifier.issn1314-7978
dc.identifier.issn1314-7471
dc.identifier.scopusSCOPUS_ID:84901653714en
dc.identifier.urihttps://rlib.uctm.edu/handle/123456789/1049
dc.language.isoen
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84901653714&origin=inward
dc.titleNanoscale particle reinforcement by oligourea particles in polyurethanes - A concept to control mechanical properties
dc.typeArticle
oaire.citation.issue3
oaire.citation.volume49
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