ELECTRODEPOSITION OF Ni-Co ALLOY POWDERS FROM DIFFERENT ELECTROLYTE COMPOSITIONS
creativework.keywords | electrodeposition, kinetic, metal powders, morphology, Ni-Co alloy | |
creativework.publisher | University of Chemical Technology and Metallurgy | en |
dc.contributor.author | Ignatova K. | |
dc.date.accessioned | 2024-07-16T11:16:50Z | |
dc.date.accessioned | 2024-07-16T11:19:00Z | |
dc.date.available | 2024-07-16T11:16:50Z | |
dc.date.available | 2024-07-16T11:19:00Z | |
dc.date.issued | 2020-01-01 | |
dc.description.abstract | The effect of the content of the main components (Co and Ni) and pH on the formation rate, the chemical com-position and the morphology of Ni-Co powders obtained in amino-sulfate, amino-chloride and chloride electrolytes is determined. The powder formation in an ammonium-sulfate electrolyte is performed with a low speed and hence a low current efficiency. It is strongly suppressed in a chloride solution by the increase of pH, Co and especially Ni content of the electrolyte. The decrease of pH from 9.1 to 1.4 increases the Ni content from 45.3 wt.% to 61.4 wt.% forming powders of a smaller average particle size (up to 10 µm) with a trend for agglomeration. The Ni-Co powders obtained have polycrystalline structures with presence of f.c.c. phases of ß-Ni and ß-Co and additional h.c.p phase of a-Co, when the cobalt content is greater than 50 wt.%. | |
dc.identifier.issn | 1314-7978 | |
dc.identifier.issn | 1314-7471 | |
dc.identifier.scopus | SCOPUS_ID:85096670301 | en |
dc.identifier.uri | https://rlib.uctm.edu/handle/123456789/1290 | |
dc.language.iso | en | |
dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85096670301&origin=inward | |
dc.title | ELECTRODEPOSITION OF Ni-Co ALLOY POWDERS FROM DIFFERENT ELECTROLYTE COMPOSITIONS | |
dc.type | Article | |
oaire.citation.issue | 6 | |
oaire.citation.volume | 55 |