Sensor activity and logic behaviour of some 2-aminoterephthalic derivatives
creativework.keywords | 2-aminoterephthalic derivatives, ICT (intramolecular charge transfer), Molecular logic gates, pH molecular sensors | |
creativework.publisher | University of Chemical Technology and Metallurgyjournal@uctm.edu | en |
dc.contributor.author | Miladinova P. | |
dc.contributor.author | Georgiev N. | |
dc.date.accessioned | 2024-07-16T11:16:46Z | |
dc.date.accessioned | 2024-07-16T11:18:00Z | |
dc.date.available | 2024-07-16T11:16:46Z | |
dc.date.available | 2024-07-16T11:18:00Z | |
dc.date.issued | 2014-01-01 | |
dc.description.abstract | Herein we report on the sensor activity of three blue-emitting triazine derivatives of 2-aminoterephthalic acid. The novelfompounds are conigured as a ``luorophore-receptor`` system. The luorophores designed can act as a pH-probe via an ``off-on-off`` luorescence sensing mechanism due to an internal charge transfer. The sensor activity towards cations and anions in water/DMF (1:1, v/v) media is studied by monitoring the luorescence intensity changes. The ions tested exert a high quenching effect suggesting that the compounds are sensitive to strong acid (pH<3) and strong alkaline media (pH>8). The logic function XNOR can be performed using an acid and a base as chemical inputs, while a digital comparator can be designed on the ground of pH induced changes in the spectral properties of the novel molecule. | |
dc.identifier.issn | 1314-7978 | |
dc.identifier.issn | 1314-7471 | |
dc.identifier.scopus | SCOPUS_ID:84920682131 | en |
dc.identifier.uri | https://rlib.uctm.edu/handle/123456789/1075 | |
dc.language.iso | en | |
dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84920682131&origin=inward | |
dc.title | Sensor activity and logic behaviour of some 2-aminoterephthalic derivatives | |
dc.type | Article | |
oaire.citation.issue | 6 | |
oaire.citation.volume | 49 |