PHASE COMPOSITION AND MICROSTRUCTURE CHARACTERIZATION OF STRONTIUM-MODIFIED BARIUM TITANATE GLASS-CERAMICS
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2023-01-01
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Abstract
Dielectric glass-ceramic materials find various applications as parts of sensors, electronic components and even in biomedicine. The present work reports on the synthesis of glass-ceramic materials in the complex oxide system (23.1-z)Na2O/17.1BaO/6SrO/23TiO2/17.4SiO2/7.6B2O3/5.8Fe2O3/zAl2O3, z = 0 and 3 mol %. The melts show spontaneous crystallization during quenching. The phase composition is studied using X-ray diffraction and reveals crystallization of Ba1-xSrxTiO3 solid solutions with varying Ba/Sr ratio. The valence states and the local environments of the Ba, Ti and Fe ions of the prepared materials are investigated by utilizing X-ray photoelectron spectroscopy. It is shown that all the elements in the composition are present in their oxidized states and the formation of barium titanate based compounds is possible. The microstructure of the obtained samples is imaged by scanning electron microscopy and shows bright polygon-like crystalline structures embedded in a dark amorphous matrix. The further evaluation of the microstructure as average crystal size and volume fraction of the precipitated crystals is done by using microcomputed tomography. Thus, a relatively high crystalline volume fraction is observed for the samples without alumina. The samples with alumina possess comparable as size and volume fraction crystals.