Synthesis, spectral properties and crystal structure of calcium and strontium complexes of 1,10-phenanthroline

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creativework.keywordsCalcium, Crystal structures, Phenanthroline, Strontium, Tetrafluoroborate ion
dc.contributor.authorNeykov M.
dc.contributor.authorVan Almsick T.
dc.contributor.authorDimitrov G.
dc.date.accessioned2024-07-10T14:27:03Z
dc.date.accessioned2024-07-10T14:46:59Z
dc.date.available2024-07-10T14:27:03Z
dc.date.available2024-07-10T14:46:59Z
dc.date.issued2006-07-19
dc.description.abstractThree new complexes of 1,10-Phenanthroline (phen), [Ca(phen) 2(H2O)2(NO3)](NO3) (1), [Sr(phen)2(H2O)2(NO3)](NO 3) (2) and [Ca(phen)2(H2O)2(NO 3)][BF4] (3) were synthesized and characterized by UV, FT IR, Raman, and MS spectra. Their crystal structures were also determined. In 1 and 2 only one of the (NO3)- is coordinated to the central atom. The other (NO3)- is away from the metal ion and was replaced by [BF4]- under the conditions of a competitive reaction. The two phenanthroline molecules also occupy nonequivalent positions showing typical π - π interactions in their crystal packing. © 2006 WILEY-VCH Verlag GmbH & Co. KGaA.
dc.identifier.doi10.1002/zaac.200500534
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.scopusSCOPUS_ID:33745911312en
dc.identifier.urihttps://rlib.uctm.edu/handle/123456789/114
dc.language.isoen
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33745911312&origin=inward
dc.titleSynthesis, spectral properties and crystal structure of calcium and strontium complexes of 1,10-phenanthroline
dc.typeArticle
oaire.citation.issue8-9
oaire.citation.volume632
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