New platinum(II) complexes of cycloalkanespiro-5-(2-thiohydantoins). Synthesis and quantum chemical investigation
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2015-01-01
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Abstract
Synthesis and characterization of new Pt(II) complexes of cyclohexanespiro-5-(2-thiohydantoin) (L1) and cyclohepta-nespiro-5-(2-thiohydantoin) (L2) are discussed. The new complexes are studied by elemental analysis, IR and <sup>1</sup>H NMR spectroscopy. The free ligands are investigated by UV-Vis, IR, <sup>1</sup>H NMR, <sup>13</sup>C NMR and Raman spectroscopy. The ground-state equilibrium geometries of the ligands L1 and L2 and their complexes with Pt(II) are optimized at the BLYP/CEP-31G theoretical level.