Synthesis of new complex [Bi6O6(OH)2](ClC6H4SO3)4and investigation of its thermal decomposition

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creativework.keywordsBi(III) complexes, FTIR, TG-DTA, Thermal decomposition, XRD
creativework.publisherScientific Publishersen
dc.contributor.authorKaloyanov N.
dc.contributor.authorZahariev A.
dc.contributor.authorParvanova V.
dc.contributor.authorAvdeev G.
dc.contributor.authorGirginov C.
dc.date.accessioned2024-07-10T14:27:06Z
dc.date.accessioned2024-07-10T14:51:02Z
dc.date.available2024-07-10T14:27:06Z
dc.date.available2024-07-10T14:51:02Z
dc.date.issued2023-05-01
dc.description.abstractA new [Bi6O6(OH)2](ClC6H4SO3)4complex is synthesized through a reaction of Bi2O3 with aqueous 4-chlorobenzenesulfonic acid at elevated temperature. The product composition is elucidated by elemental analysis, ICP-OES and FTIR techniques. By means of XRD analysis, the compound s indexation, monoclinic P2(3) space group and unit cell parameters: A=31.25(3) A, b=19.78(1) A, c=8.795(8) A, γ = 94.33(4)o as well as a cell volume = 5424.21 A3 are determined. Based on DTA-TG technique, three specific temperatures aimed at studying product s thermal decomposition are determined. The compositions of solid residues after isothermal heating are proved following the XRD and FTIR data.
dc.identifier.doi10.56042/ijc.v62i5.1434
dc.identifier.issn2583-1321
dc.identifier.scopusSCOPUS_ID:85164564554en
dc.identifier.urihttps://rlib.uctm.edu/handle/123456789/848
dc.language.isoen
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85164564554&origin=inward
dc.titleSynthesis of new complex [Bi6O6(OH)2](ClC6H4SO3)4and investigation of its thermal decomposition
dc.typeArticle
oaire.citation.issue5
oaire.citation.volume62
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